Highly Functional TNTs with Superb Photocatalytic,Optical, and Electronic Performance Achieving Record PV Efficiency of 10.1% for 1D‐Based DSSCs

Different nanostructures of TiO₂ play an important role in the photocatalytic and photoelectronic applications. TiO₂ nanotubes (TNTs) have received increasing attention for these applications due to their unique physicochemical properties. Focusing on highly functional TNTs (HF‐TNTs) for photocatalytic and photoelectronic applications, this study describes the facile hydrothermal synthesis of HF‐TNTs by using commercial and cheaper materials for cost‐effective manufacturing. To prove the functionality and applicability, these TNTs are used as scattering structure in dye‐sensitized solar cells (DSSCs). Photocatalytic, optical, Brunauer‐Emmett‐Teller (BET), electrochemical impedance spectrum, incident‐photon‐to‐current efficiency, and intensity‐modulated photocurrent spectroscopy/intensity‐modulated photovoltage spectroscopy characterizations are proving the functionality of HF‐TNTs for DSSCs. HF‐TNTs show 50% higher photocatalytic degradation rate and also 68% higher dye loading ability than conventional TNTs (C‐TNTs). The DSSCs having HF‐TNT and its composite‐based multifunctional overlayer show effective light absorption, outstanding light scattering, lower interfacial resistance, longer electron lifetime, rapid electron transfer, and improved diffusion length, and consequently, J _SC, quantum efficiency, and record photoconversion efficiency of 10.1% using commercial N‐719 dye is achieved, for 1D‐based DSSCs. These new and highly functional TNTs will be a concrete fundamental background toward the development of more functional applications in fuel cells, dye‐sensitized solar cells, Li‐ion batteries, photocatalysis process, ion‐exchange/adsorption process, and photoelectrochemical devices.     

Organometallic Bonding in an Ullmann‐Type On‐Surface Chemical Reaction Studied by High‐Resolution Atomic Force Microscopy

The on‐surface Ullmann‐type chemical reaction synthesizes polymers by linking carbons of adjacent molecules on solid surfaces. Although an organometallic compound is recently identified as the reaction intermediate, little is known about the detailed structure of the bonded organometallic species and its influence on the molecule and the reaction. Herein atomic force microscopy at low temperature is used to study the reaction with 3,9‐diiododinaphtho[2,3‐b:2′,3′‐d]thiophene (I‐DNT‐VW), which is polymerized on Ag(111) in vacuum. Thermally sublimated I‐DNT‐VW picks up a Ag surface atom, forming a C? Ag bond at one end after removing an iodine. The C? Ag bond is usually short‐lived, and a C? Ag? C organometallic bond immediately forms with an adjacent molecule. The existence of the bonded Ag atoms strongly affects the bending angle and adsorption height of the molecular unit. Density functional theory calculations reveal the bending mechanism, which reveals that charge from the terminus of the molecule is transferred via the Ag atom into the organometallic bond and strengths the local adsorption to the substrate. Such deformations vanish when the Ag atoms are removed by annealing and C? C bonds are established.     

Optimum lipid production using agro-industrial wastewater treated microalgae as biofuel substrate

Abundant wastewater discharges from palm oil industries in tropical nations being a valuable resource of biodiesel need proper exploration. Research hinted that such wastewater as economical nutrient source or substrate can support the cultivation of microalgae. In this experiment, we have tested the growth and lipid production of five different microalgal strains in palm oil mill effluent (POME). POME as a biofuel substrate is demonstrated to be lucrative for microalgae-assisted lipids production. POME is rich in macro- and micronutrients can be used as a growth medium for algal growth in order to reduce the growth medium cost and environmental pollutions. Among the five microalgal strains tested, Chlorella sorokiniana revealed optimum biomass and lipid production. The productivity was evaluated in terms of chlorophyll content, growth rate, biomass, and lipid content, which discerned to be 0.099/day, 8.0 mg/L day and 2.68 mg/mg cell dry weight (CDW). Furthermore, in this study, an optimization study was carried out to enhance the microalgae to produce high lipid content using carbon-to-nitrogen ratio and different light/dark periods. The presence of nitrogen combined glucose (with a carbon-to-nitrogen ratio 100:7) as an alternative source to carbon displayed higher lipid production of 2.68 (mg/mg CDW) by C. sorokiniana. This study confirms that 8:16 h light/dark condition at C:TN ratio of 100:7 supported to produce high lipid content of 17 mg lipid/mg CDW. The above results revealed that POME could be a suitable growth media for the alga C. sorokiniana to improve the maximum lipid yield for biofuels production.     

Discriminative functional analysis of human movements

This paper investigates the use of statistical dimensionality reduction (DR) techniques for discriminative low dimensional embedding to enable affective movement recognition. Human movements are defined by a collection of sequential observations (time-series features) representing body joint angle or joint Cartesian trajectories. In this work, these sequential observations are modelled as temporal functions using B-spline basis function expansion, and dimensionality reduction techniques are adapted to enable application to the functional observations. The DR techniques adapted here are: Fischer discriminant analysis (FDA), supervised principal component analysis (PCA), and Isomap. These functional DR techniques along with functional PCA are applied on affective human movement datasets and their performance is evaluated using leave-one-out cross validation with a one-nearest neighbour classifier in the corresponding low-dimensional subspaces. The results show that functional supervised PCA outperforms the other DR techniques examined in terms of classification accuracy and time resource requirements.     

Efficient routing techniques in heterogeneous 3D Networks-on-Chip

Three-dimensional Networks-on-Chips (3D NoCs) have recently been proposed to address the on-chip communication demands of future highly dense 3D multi-core systems. Homogeneous 3D NoC topologies have many Through Silicon Vias (TSVs) which have a costly and complex manufacturing process. Also, 3D routers use more memory and are more power hungry than conventional 2D routers. Alternatively, heterogeneous 3D NoCs combine both the area and performance benefits of 2D and 3D static router architectures by using a limited number of TSVs. To improve the performance of heterogeneous 3D NoCs, we propose an adaptive router architecture which balances the traffic in such NoCs. Particularly, experimental results show that our proposed architecture significantly improves the performance up to 75% by replacing 2D static routers with adaptive 2D routers in heterogeneous 3D NoCs, while keeping the maximum clock frequency, power and energy consumption of the adaptive router nearly at the same level as the static router.     

Minimizing ordered weighted averaging of rational functions with applications to continuous location

This paper considers the problem of minimizing the ordered weighted average (or ordered median) function of finitely many rational functions over compact semi-algebraic sets. Ordered weighted averages of rational functions are, in general, neither rational functions nor the supremum of rational functions so current results available for the minimization of rational functions cannot be applied to handle these problems. We prove that the problem can be transformed into a new problem embedded in a higher dimensional space where it admits a convenient polynomial optimization representation. This reformulation allows a hierarchy of SDP relaxations that approximates, up to any degree of accuracy, the optimal value of those problems. We apply this general framework to a broad family of continuous location problems showing that some difficult problems (convex and non-convex) that up to date could only be solved on the plane and with Euclidean distance can be reasonably solved with different _?p-norms${?}_p\mathrm{-}\mathrm{norms}$ in finite dimensional spaces. We illustrate this methodology with some extensive computational results on constrained and unconstrained location problems.     

Bridge the gap between statistical and hand-crafted grammars

LTAG is a rich formalism for performing NLP tasks such as semantic interpretation, parsing, machine translation and information retrieval. Depend on the specific NLP task, different kinds of LTAGs for a language may be developed. Each of these LTAGs is enriched with some specific features such as semantic representation and statistical information that make them suitable to be used in that task. The distribution of these capabilities among the LTAGs makes it difficult to get the benefit from all of them in NLP applications.This paper discusses a statistical model to bridge between two kinds LTAGs for a natural language in order to benefit from the capabilities of both kinds. To do so, an HMM was trained that links an elementary tree sequence of a source LTAG onto an elementary tree sequence of a target LTAG. Training was performed by using the standard HMM training algorithm called Baum–Welch. To lead the training algorithm to a better solution, the initial state of the HMM was also trained by a novel EM-based semi-supervised bootstrapping algorithm.The model was tested on two English LTAGs, XTAG (XTAG-Group, 2001) and MICA's grammar (Bangalore et al., 2009) as the target and source LTAGs, respectively. The empirical results confirm that the model can provide a satisfactory way for linking these LTAGs to share their capabilities together.     

Multi-Fault Tolerance for Cartesian Data Distributions

Faults are expected to play an increasingly important role in how algorithms and applications are designed to run on future extreme-scale systems. Algorithm-based fault tolerance is a promising approach that involves modifications to the algorithm to recover from faults with lower overheads than replicated storage and a significant reduction in lost work compared to checkpoint-restart techniques. Fault-tolerant linear algebra algorithms employ additional processors that store parities along the dimensions of a matrix to tolerate multiple, simultaneous faults. Existing approaches assume regular data distributions (blocked or block-cyclic) with the failures of each data block being independent. To match the characteristics of failures on parallel computers, we extend these approaches to mapping parity blocks in several important ways. First, we handle parity computation for generalized Cartesian data distributions with each processor holding arbitrary subsets of blocks in a Cartesian-distributed array. Second, techniques to handle correlated failures, i.e., multiple processors that can be expected to fail together, are presented. Third, we handle the colocation of parity blocks with the data blocks and do not require them to be on additional processors. Several alternative approaches, based on graph matching, are presented that attempt to balance the memory overhead on processors while guaranteeing the same fault tolerance properties as existing approaches that assume independent failures on regular blocked data distributions. Evaluation of these algorithms demonstrates that the additional desirable properties are provided by the proposed approach with minimal overhead.     

Case study on handoff strategies for wireless overlay networks

One of the most challenging topics for next‐generation wireless networks is the process of vertical handoff since many of wireless technologies overlap each other and build a heterogeneous topology. Several parameters, pertaining to user/application requirements and network conditions, such as data rate, service cost, network latency, speed of mobile, and etc. must be considered in the handoff process of heterogeneous networks along with RSSI information. In this paper, adaptive fuzzy logic‐based vertical handoff decision‐making algorithms are presented for wireless overlay networks which consist of GSM/GPRS/Wi-Fi/UMTS/WiMAX technologies. The parameters data rate, monetary cost, speed of mobile and RSSI information are processed as inputs of the proposed fuzzy‐based systems. According to these parameters, an output value, which varies between 1 and 10, is produced. This output value is utilized to determine whether a handoff process is necessary or not and to select the best candidate access point in the vicinity. The results show that, compared to the traditional RSSI‐based algorithm significantly enhanced outcomes can be achieved for both user and network as a consequence of the proposed fuzzy‐based handoff systems. The simulation results are also compared with those of classical MADM (Multiple Attribute Decision Making) method, i.e. SAW (Simple Additive Weighting). According to the results obtained, the proposed vertical handoff decision algorithms are able to determine whether a handoff is necessary or not, properly, and select the best candidate access network considering the aforementioned parameters. Moreover, fuzzy‐based algorithm noticeably reduces the number of handoffs compared to SAW‐based algorithm.     

Enhanced dynamic credential generation scheme for protection of user identity in mobile-cloud computing

To improve the resource limitation of mobile devices, mobile users may utilize cloud-computational and storage services. Although the utilization of the cloud services improves the processing and storage capacity of mobile devices, the migration of confidential information on untrusted cloud raises security and privacy issues. Considering the security of mobile-cloud-computing subscribers’ information, a mechanism to authenticate legitimate mobile users in the cloud environment is sought. Usually, the mobile users are authenticated in the cloud environment through digital credential methods, such as password. Once the users’ credential information theft occurs, the adversary can use the hacked information for impersonating the mobile user later on. The alarming situation is that the mobile user is unaware about adversary’s malicious activities. In this paper, a light-weight security scheme is proposed for mobile user in cloud environment to protect the mobile user’s identity with dynamic credentials. The proposed scheme offloads the frequently occurring dynamic credential generation operations on a trusted entity to keep minimum processing burden on the mobile device. To enhance the security and reliability of the scheme, the credential information is updated frequently on the basis of mobile-cloud packets exchange. Furthermore, the proposed scheme is compared with the existing scheme on the basis of performance metrics i.e. turnaround time and energy consumption. The experimental results for the proposed scheme showed significant improvement in turnaround time and energy consumption as compared to the existing scheme.